For good resistance to h 2 sinduced stress corrosion cracking scc an alloy with high nickel content is recommended, and for most sour environments this type of alloy is now used. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Resistance to stress corrosion cracking haynes international. Guideline for the materials selection and corrosion. The resistance of metals to stress corrosion cracking is always less when tension is applied in a transverse direction.
Corrosion materials is a global leader in specialty nickel alloys. A good selection of alloys is available for service in highly corrosive environments. Stress corrosion cracking in aluminum alloys is characteristically intergranular. Scc in service, and guidelines are given for preventing and alleviating these problems. Like many other nickel alloys, it is ductile, easily formed and welded. This document sets forth the criteria to be used in the selection of materials for space vehicles and associated equipment and facilities so that. Selecting aluminum alloys to resist failure by fracture. Superduplex steels that resist corrosion in demanding. According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion propagates selectively along them. Astm g649920, standard classification of resistance to stress corrosion cracking of heattreatable aluminum alloys, astm international, west conshohocken, pa, 20. However, contrary to popular belief, they are prone to failures from corrosion, including intergranular corrosion as a result of welding, stress corrosion cracking, and microbiologically induced corrosion mic. Paul woollin, twi and manuel maligas, fmc corporation.
Stress corrosion cracking scc is interpreted to take place due to specific combinations of susceptible materials in suitable corrosion environments under adequate stress, specifically under constant stress, figure 1. This material is susceptible to stress corrosion cracking in sour brines, and thus the use of this material is restricted according to the limits detailed in iso 15156nace mr0175, which are detailed in table 1. Heat exchanger material selection based on common criteria. Stress corrosion cracking is a form of localised failure which is more severe under the combined action of stress and corrosion than would be expected from the sum of the individual effects acting alone. Mild steel is a wellknown structured material in the petroleum industry due to its low cost, good mechanical and corrosion resistant properties. Materials in the sour environment are susceptible to sulfide stress corrosion cracking ssc and hydrogeninduced cracking, hydrogen embrittlement and exfoliation hehic that leads to various modes of failure including stepwise cracking, hence the importance during the design stage on material selection. Scc is highly chemically specific in that certain alloys are likely. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. For the susceptibility to stress corrosion cracking, the directional variation can be appreciable and must be considered in the design of the fabricated hardware. Elevated stress susceptible material corrosive environment surface contamination by atmospheric chlorides sufficient humidity epri has a multiyear project to. Chloride induced stress corrosion cracking ciscc of stainless steel reactor components has occurred when three elements are all present. This document does not intend to include all factors and criteria necessary for the total control of stress.
The high nickel alloys are also very resistant to stress corrosion cracking in waters containing chlorides, which may otherwise affect the lower alloyed 300 series stainless steels. Of the stainless steels, a286 is the best fastener material for aerospace. Dec 02, 2019 however, there are also cases where carbon steel offers better resistance to stress corrosion cracking than stainless steel, so the risks of rust corrosion need to be weighed against stress corrosion cracking during material selection. If cracks are observed during evaluation, and if criteria for approval shall be based on crack depth, cross sections of the material around the crack s will be prepared and crack depth will be measured using optical microscopy. Corrosion resistant material corrosion resistant stainless. Mechanical requirements, such as a high yield strength, can be very difficult to reconcile with scc resistance especially where. Sour service limits of dualcertified 316316l steel twi.
The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. It is especially important to avoid any mechanical tensile stress concentration, which will occur at sharp edges and notches. This standard is one of the series of ecss standards intended to be. Stress corrosion is a form of galvanic corrosion, where stressed areas of the material are anodic to the unstressed areas of the material. The equivalent mechanism for crack growth under cyclic stresses is called corrosion fatigue cf. Corrosion performance and fabricability of the new gen. Stress corrosion cracking behavior of nickel base alloys. They generally have comparable or better corrosion resistance to austenitic steels, with more than twice the yield strength, and are especially resistant to pitting corrosion and stress corrosion cracking in chloride environments. Stress corrosion cracking sandvik materials technology. Jan 31, 2016 in contrast to hsc and ssc, stress corrosion cracking scc, defined as the cracking of a material produced by the combined action of corrosion and sustained tensile stress residual or applied, is an anodic process that takes place in a region where. Stress corrosion cracking control measures nist page. These tests are conducted to examine and evaluate the behavior, susceptibility, and extent of resistance of certain materials to stress corrosion cracking, cavitation erosion, intergranular corrosion, pitting and crevice corrosion, cyclic potentiodynamic polarization, exfoliation corrosion, atmospheric and galvanic corrosion, liquid impingement erosion, crevice repassivation, sliding and rolling friction, surface scratching and lubrication, cavitating liquid jet erosion, and hydrogen. The fastener material manufacturers have been forced to develop alloys that are less sensitive to stress corrosion.
It is the least for the short transverse direction. For the purposes of this document, corrosion includes general and localized corrosion mechanisms, as well as environmental cracking mechanisms including, but not limited to, stress corrosion cracking scc, sulfide stress cracking. The presence of some pollutants, mainly sulfide, in the oil itself can affect the performance of mild steel in the petrochemical industry. A common solution for assessing the resistance of materials to this extremely destructive form of attack is boiling 45% magnesium chloride astm standard g 36. In many cases, problems with stress corrosion cracking scc can be solved by selecting a suitable material. The materials excellent resistance to stress corrosion cracking scc, pitting and crevice corrosion in chloride bearing environments makes it a natural choice for hydraulic and instrumentation tubing applications on offshore platforms. Figure 1 astm 316l stainless steel and sandvik saf 2507.
Corrosion standards and wear standards astm international. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Nickel alloys with a pren number greater than 40 are very resistant to crevice corrosion in seawater. There are a set or sets of environmental conditions in which most metals can exhibit stress corrosion cracking. Any cracking caused by stress corrosion is evaluated after exposure using optical microscopy. Corrosion resistant material in normal mechanical and structural engineering design materials are selected primarily for their mechanical properties corrosion is not an important criteria. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. The systems are generally protected against corrosion by surface coatings. Ecssqst7036c material selection for controlling stress. Superduplex stainless steels are widely used by the oil and gas industry for their combination of corrosion resistance, chloride stress corrosion cracking resistance, high strength and weldability. Comparison of the resistance to stress corrosion of various aluminum alloys and products ref. The risk of stress corrosion cracking scc can be minimized through plant and equipment design.
In general, the higher the heattreating temperature of the material and the lower the ductility, the more susceptible it is to stress corrosion cracking. Stress corrosion cracking scc results from the combined action of three factors. Thus, to take full advan tage of the corrosion resistant properties of stainless steel. Susceptibility assessment criteria for chlorideinduced. Testing of superduplex stainless steel for sour service.
Standard classification of resistance to stresscorrosion. Carpenter selecting alloys for severely corrosive environments. It is intended to provide general criteria to be used in stress. They should be considered for use only in cases where a suitable alloy cannot be found in table i. Optimum selection and use of fatigue resistant aluminum alloys also has become more of a factor for designers and materials engineers for extending fatigue life andor structural effi ciency. Stresscorrosion cracking, materials performance and. Stress corrosion cracking scc is defined as the growth of cracks due to the. Scc resistance especially where hydrogen embrittlement is involved. Nickel alloys alloy c276 alloy c276 is a solid solution strengthened nickelmolybdenumchromium alloy with a small amount of tungsten.
Alloy c276 exhibits excellent corrosion resistance in a variety of harsh environments and media. Alloys of the 6xxx series show a strong resistance to stress corrosion cracking as. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Material selection for sour service environment pipeline. The stress corrosion cracking susceptibility of the precipitation hardening stainless steels generally increased with increasing hardness or strength, but in certain cases appears to be associated with. Stress corrosion school of materials science and engineering. Mechanisms of stresscorrosion cracking asm international. Selection of metallic materials for stress corrosion cracking resistance in sodium chloride environments 1. Scc table ii alloys and tempers listed in table ii are moderately resistant to stress corrosion cracking. The limits for 316316l were considered to be conservative by industry but adequate data were not available to modify them. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media.
Stress corrosion cracking scc near the fusion boundary of a 316ng stainless steel ss welded joint in hightemperature water was investigated with emphasis on the relation to the. Stresscorrosion cracking materials performance and evaluation. Materials that testing and experience have shown to possess high resistance to stress corrosion cracking their use is given reference. This new second edition serves as a go to reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. An important responsibility of the vational bureau of standards is. Improved resistance to caustic stress corrosion cracking can be given to. This document defines the design criteria that shall be used for the selection of metallic materials in order to prevent failure due to stress corrosion cracking. The impact of scc on a material usually falls between dry cracking and the fatigue. Stress corrosion cracking scc sandvik materials technology. Mechanical requirements, such as a high yield strength, can be. A sandvik grade with very good resistance to this form of stress corrosion cracking is sanicro 28.
Fernandez, joseph rogelio, stress corrosion cracking evaluation of candidate high strength stainless steels for prestressed concrete 2011. Stress corrosion cracking behavior of nickel base alloys by alloy typical corrosion resistant nickel based super alloys are a solid solution nickel whilst few are precipitation hardened materials uch as in 718, 625 and x750. Determination of stress corrosion resistance of copper alloys. Guidelines for using stainless steel in the water and. Thermal treatment in fabrication can be a determining factor. Stress corrosion cracking an overview sciencedirect topics. By choosing a material that is not susceptible to scc in the service. Scc usually occurs in certain specific alloyenvironmentstress combinations. Welding or stress relieving, for example, can affect resistance to corrosion, particularly to stress corrosion cracking and intergranular corrosion. The corrosivity of such solutions is affected by acidity and chloride content. Copper and cuni have moderate corrosion resistance but tend to discolor and scale easily.664 590 736 465 1146 1352 131 1549 531 1423 691 418 595 556 619 863 1547 169 281 865 177 370 458 1407 926 787 421 1196 862 682 114 297 283 440 1012 1039 700 23 1482 1498 1022 1332 1168 1143 1304 1375 603 1370